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Panache is the way someone does something. Charisma is whether the person doing it is likable and charming.
A great actor or a politician has charisma.
A snake oil salesman has panache.
Panache is one thing that can contribute to charisma.
Panache is flair. It’s a certain sort of showy style in how you act.
Charisma is habitually making people like you.
I see charisma as an innate quality and panache is something you put on.